Modified Fly Ash: An Eco-Friendly, Cost-Free, and Efficient Iron-Based Catalyst for Ammonia Decomposition to COx-Free Hydrogen
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Tarih
2024
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Wiley-V C H Verlag Gmbh
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Fly ash (FA), an industrial waste produced in large amounts, is rich in metal oxides such as Al2O3, SiO2, and Fe2O3, making it an ideal candidate for use as a catalyst in ammonia decomposition. However, FA's surface area is very low (<1.0 m(2) g(-1)), limiting its potential. This study investigates the modification of FA by calcination at various temperatures (550, 700, and 1000 degrees C), HCl treatment, and HCl treatment followed by calcination at 500 degrees C to convert FA into a catalyst by utilizing its iron content as active sites. The catalyst obtained by treating FA with HCl at 220 degrees C, calcining at 500 degrees C, reducing in H-2 at 700 degrees C, and activating in ammonia at 700 degrees C achieved 86.0% ammonia conversion at a reaction temperature of 700 degrees C and a space velocity of 30,000 mL NH3 h(-1) gcat(-1), remaining stable for 140 h following an induction period of 30 h. Enhanced textural properties (18.5 m(2) g(-1)), elimination of S and Cl impurities, and the formation of relatively small Fe crystallites (23.8 nm determined by Scherrer equation and 24.0 nm measured by transmission electron microscopy (TEM)) when reduced in H-2 were responsible for this performance.
Açıklama
Anahtar Kelimeler
Acid modification, Ammonia decomposition, Catalysis, Fly ash, Hydrogen
Kaynak
Chemcatchem
WoS Q Değeri
Q2
Scopus Q Değeri
Q1
