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Active sites and their individual turnover frequencies for ethylene hydrogenation on reduced graphene aerogel
Kurtoğlu-Öztulum, Samira Fatma; Yalçın, Kaan; Saraç Öztun, F. Eylül; Kanat, Gizem Hasibe; Ünal, Uğur; Uzun, Alper (American Chemical Society, 2024)Graphene aerogel (GA) was reduced at various temperatures to prepare a series of reduced graphene aerogels (rGAs) with different surface characteristics. Detailed characterization demonstrated that an increase in the thermal ... -
Atomically dispersed zeolite-supported rhodium complex: Selective and stable catalyst for acetylene semi-hydrogenation
Kurtoğlu-Öztulum, Samira Fatma; Zhao, Yuxin; Hoffman, Adam S.; Uzun, Alper; Demircan, Oktay; Yordanli, Melisa Su; Hong, Jiyun; Perez-Aguilar, Jorge E.; Saltuk, Aylin; Akgül, Deniz; Ateşin, Tülay A.; Aviyente, Viktorya; Gates, Bruce C.; Bare, Simon R. (Elsevier, 2024)Supported rhodium catalysts are known to be unselective for semi-hydrogenation reactions. Here, by tuning the electronic structure of supported mononuclear rhodium sites determined by the metal nuclearity and the electron-donor ... -
Challenges with atomically dispersed supported metal catalysts: Controllingperformance, improving stability, and enhancing metal loading
Kurtoğlu-Öztulum, Samira Fatma; Uzun, Alper (Elsevier, 2023)Comprehensive Inorganic Chemistry III, a ten-volume reference work, is intended to cover fundamental principles, recent discoveries, and significant applications of elements and their compounds. Authored by renowned experts ... -
Reduced graphene aerogel-supported Ir(C2H4)2 complexes at an exceptional Ir loading of 23.8 wt%: Confirming site-isolation by combining XAS and STEM
Kurtoğlu-Öztulum, Samira Fatma; Yalçın, Kaan; Zhao, Yuxin; Ünal, Uğur; Uzun, Alper (Turkish Catalysis Society, 2023)Atomically dispersed supported metal catalysts offer significant opportunities when compared to conventional analogues. They provide maximum utilization of expensive noble metals, interesting catalytic properties, and ...