Characteristic Influence of Cerium Ratio on PrMn Perovskite-Based Cathodes for Solid Oxide Fuel Cells

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dc.contributor.authorKaraismailoğlu Elibol, Meltem
dc.contributor.authorBalkanlı Ünlü, Esra
dc.contributor.authorFigen, Halit Eren
dc.date.accessioned2026-02-12T09:57:20Z
dc.date.available2026-02-12T09:57:20Z
dc.date.issued2025
dc.departmentTAÜ, Fen Fakültesi, Enerji Bilimi ve Teknolojileri Bölümü
dc.description.abstractIn this study, cerium with different ratios (x = 0 (zero), 0.1, 0.15, 0.5) was added to the PrMn structure as an A-site material to evaluate characteristic behavior as a potential cathode material for solid oxide fuel cells. The PrxCe1−xMnO3−δ electrocatalysts were synthesized using the sol–gel combustion method and were assessed for their electrochemical, phase, and structural properties, as well as desorption and reducibility capabilities. Phase changes, from orthorhombic to cubic structures observed upon cerium additions, were evaluated via the X-Ray diffraction method. X-Ray photoelectron spectroscopy (XPS) showed the valence states of the surface between the Ce4+/Ce3+ and Pr4+/Pr3+ redox pairs, while oxygen temperature programmed desorption (O2-TPD) analysis was used to evaluate the oxygen adsorption and desorption behavior of the electrocatalysts. Redox characterization, evaluated via hydrogen atmosphere temperature-programmed reduction (H2-TPR), revealed that a higher cerium ratio in the structure lowered the reduction temperature, suggesting a better dynamic oxygen exchange capability at a lower temperature for the Pr0.5Ce0.5MnO3−δ catalyst compared to the electrochemical behavior analysis by the electrochemical impedance spectroscopy method. Moreover, the symmetrical cell tests with Pr0.5Ce0.5MnO3−δ electrodes showed that, when combined with scandia-stabilized zirconia (ScSZ) electrolyte, the overall polarization resistance was reduced by approximately 28% at 800 °C compared to cells with yttria-stabilized zirconia (YSZ) electrolyte
dc.identifier.citationBalkanlı Ünlü, E., Karaismailoğlu Elibol, M., Figen, Halit E. Characteristic Influence of Cerium Ratio on PrMn Perovskite-Based Cathodes for Solid Oxide Fuel Cells. Catalysts 2025, 15 (8), 786.
dc.identifier.doi10.3390/catal15080786
dc.identifier.issue8
dc.identifier.startpage786
dc.identifier.urihttps://hdl.handle.net/20.500.12846/2133
dc.identifier.volume15
dc.institutionauthorid0000-0003-3514-3768
dc.language.isoen
dc.relation.ispartofCatalysts
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectsolid oxide fuel cell
dc.subjectscandia-stabilized zirconia
dc.subjectpraseodymium catalyst
dc.subjectPrCeMn
dc.subjectcathode
dc.subjectelectrolyte comparison
dc.titleCharacteristic Influence of Cerium Ratio on PrMn Perovskite-Based Cathodes for Solid Oxide Fuel Cells
dc.typeArticle

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